Electrospray ionisation (ESI)

Electrospray ionisation (ESI)

The Electrospray Ionization (ESI) technique allows to bring molecules and compounds like biomolecules, nanoparticles and complexes as intact and isolated charged units in the gas phase.
Mass spectrometry, is a powerful tool for a variety of analytical applications and is ideally suited for the preparation of charged molecules with well-defined compositions and charge state. The combination of an ESI-source and a set-up for mass spectrometry in the custom-made instrument under construction at ISM will allow to select and deposit mass- and charge-selected ions of several different materials on surfaces.
The ESI source operates at ambient pressure and the produced molecular ions are transported in vacuum via a differential pumping section. A system of electrostatic lenses and an octupole remove most of the contaminations from neutral species and solvent molecules, transporting the ion beam into a quadrupole mass filter (QMS), operated in high vacuum, which performs the mass/charge selection. An electrostatic deflector then directs the beam either to a characterization section or to a “soft-landing” deposition chamber. A third line for gas phase spectroscopy will be implemented in the near future. 

ESI

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